Single-particle and two-particle quantum numbers

We operate with $$ \hat{j}^2=(\hat{l}+\hat{s})^2=\hat{l}^2+\hat{s}^2+2\hat{l}_z\hat{s}_z+\hat{l}_+\hat{s}_{-}+\hat{l}_{-}\hat{s}_{+} $$ on the two \( jm_j \) states, that is $$ \hat{j}^2\psi_{n=0j=5/2m_j=3/2;l=2s=1/2}= \alpha\hbar^2[l(l+1)+\frac{3}{4}+2m_lm_s]\phi_{n=0l=2m_l=2s=1/2m_s=-1/2}+ $$ $$ \beta\hbar^2\sqrt{l(l+1)-m_l(m_l-1)}\phi_{n=0l=2m_l=1s=1/2m_s=1/2}, $$ and $$ \hat{j}^2\psi_{n=0j=3/2m_j=3/2;l=2s=1/2}= \alpha\hbar^2[l(l+1)+\frac{3}{4}+2m_lm_s]+ \phi_{n=0l=2m_l=1s=1/2m_s=1/2}+ $$ $$ \beta\hbar^2\sqrt{l(l+1)-m_l(m_l+1)}\phi_{n=0l=2m_l=2s=1/2m_s=-1/2}. $$