The Hamiltonian matrix will have smaller dimensions (a factor of 10 or more) in the J -scheme than in the M -scheme. On the other hand, as we'll show in the next slide, the M -scheme is very easy to construct with Slater determinants, while the J -scheme basis states, and thus the matrix elements, are more complicated, almost always being linear combinations of M -scheme states. J -scheme bases are important and useful, but we'll focus on the simpler M -scheme.
The quantum number m is additive (because the underlying group is Abelian): if a Slater determinant \hat{a}_i^\dagger \hat{a}^\dagger_j \hat{a}^\dagger_k \ldots | 0 \rangle is built from single-particle states all with good m , then the total M = m_i + m_j + m_k + \ldots This is not true of J , because the angular momentum group SU(2) is not Abelian.