The upshot is that
- It is easy to construct a Slater determinant with good total \( M \);
- It is trivial to calculate \( M \) for each Slater determinant;
- So it is easy to construct an \( M \)-scheme basis with fixed total \( M \).
Note that the individual \( M \)-scheme basis states will
not, in general,
have good total \( J \).
Because the Hamiltonian is rotationally invariant, however, the eigenstates will
have good \( J \). (The situation is muddied when one has states of different \( J \) that are
nonetheless degenerate.)